First eddy covariance flux measurements of semi-volatile organic compounds with the PTR3-TOF-MS

نویسندگان

چکیده

Abstract. We present first eddy covariance flux measurements with the PTR3-TOF-MS, a novel proton transfer time of flight reaction mass spectrometer. During 3 weeks in spring 2016, instrument recorded 10 Hz data biogenic volatile organic compounds above boreal forest, on top measurement tower at SMEAR (Station for Measuring Ecosystem –Atmosphere Relations) II station Hyytiälä, Finland. Flux and concentration isoprene, monoterpenes, sesquiterpenes were compared to literature. Due improved sensitivity customized wall-less inlet design, we could detect fluxes semi-volatile low-volatility less than single-digit picomol per square meter second (pmolm-2s-1) values time. These include sesquiterpene oxidation products diterpenes. Daytime diterpene range 0.05 0.15 pmolm-2s-1, which amounts about 0.25 % 0.5 daytime canopy.

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ژورنال

عنوان ژورنال: Atmospheric Measurement Techniques

سال: 2021

ISSN: ['1867-1381', '1867-8548']

DOI: https://doi.org/10.5194/amt-14-8019-2021